It's a very clever trick: a refrigerator without a compressor that uses heat as the energy source. It could run on either a gas flame or an electric heating element.
There are three working fluids (butane, water and ammonia) and it works by exploiting differences in partial pressure (that is, the pressure contributed by each component of a mixture). Instead of using a compressor to change the overall pressure, it changes the composition of the gas mixture.
The cycle basically works by adding and removing ammonia at different points to make the butane refrigerant evaporate and condense in the appropriate places.
On the "condenser" side of things, water is used to remove the ammonia from the gas mixture by absorption. Because the total pressure is approximately the same throughout the system, removing ammonia increases the butane mole fraction and therefore its partial pressure, causing the butane to condense. This is the heat rejection side.
On the evaporator side, ammonia is added again. This lowers the butane partial pressure, shifting the equilibrium and causing the liquid butane to evaporate. That's where the cooling effect occurs.
The other part of the cycle is regenerating the ammonia by separating it from the water again. That's where heat is added, and that heat input is what ultimately drives the process.
> The three working fluids in this design are water, ammonia, and butane. [1] The Einstein refrigerator (co-invented with Leó Szilárd) was actually a modification of an earlier three-fluid absorption design created by Swedish engineers Baltzar von Platen and Carl Munters
There are three working fluids (butane, water and ammonia) and it works by exploiting differences in partial pressure (that is, the pressure contributed by each component of a mixture). Instead of using a compressor to change the overall pressure, it changes the composition of the gas mixture.
The cycle basically works by adding and removing ammonia at different points to make the butane refrigerant evaporate and condense in the appropriate places.
On the "condenser" side of things, water is used to remove the ammonia from the gas mixture by absorption. Because the total pressure is approximately the same throughout the system, removing ammonia increases the butane mole fraction and therefore its partial pressure, causing the butane to condense. This is the heat rejection side.
On the evaporator side, ammonia is added again. This lowers the butane partial pressure, shifting the equilibrium and causing the liquid butane to evaporate. That's where the cooling effect occurs.
The other part of the cycle is regenerating the ammonia by separating it from the water again. That's where heat is added, and that heat input is what ultimately drives the process.
Einstein–Szilard refrigerator: https://en.wikipedia.org/wiki/Einstein_refrigerator :
> The three working fluids in this design are water, ammonia, and butane. [1] The Einstein refrigerator (co-invented with Leó Szilárd) was actually a modification of an earlier three-fluid absorption design created by Swedish engineers Baltzar von Platen and Carl Munters